Can't seem to find any psd file.
There is this site...
http://www.gelaskins.com/store/gaming/PS3_Controll
If you go into one of the designs, it has the layout there. You can actually remove the background from it. Then take a screen shot and create a template from that - it has the outline of the controller.
Not 100% what you were after but may help.
cheers.
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